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Zirconocene Dichloride Catalyzed Hydrodefluorination of C sp 2 F bonds
Author(s) -
Yow Shuhui,
Gates Sarah J.,
White Andrew J. P.,
Crimmin Mark R.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201207036
Subject(s) - catalysis , chemistry , aluminium , terminal (telecommunication) , metal , medicinal chemistry , polymer chemistry , combinatorial chemistry , organic chemistry , computer science , telecommunications
A two‐metal job : Four‐coordinate aluminum dihydrides such as 1 are reported as terminal reductants for the selective title reaction. The heterobimetallic complex 2 has been isolated and shown to be catalytically competent.