Diverse Reactivity in a Rhodium(III)‐Catalyzed Oxidative Coupling of  N ‐Allyl Arenesulfonamides with Alkynes | Zendy

Wang Dongqi | Zendy; Wang Fen | Zendy; Song Guoyong | Zendy; Li Xingwei | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Diverse Reactivity in a Rhodium(III)‐Catalyzed Oxidative Coupling of N ‐Allyl Arenesulfonamides with Alkynes

Author(s) -

Wang Dongqi,

Wang Fen,

Song Guoyong,

Li Xingwei

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206918

Subject(s) - reactivity (psychology) , rhodium , chemistry , catalysis , medicinal chemistry , oxidative phosphorylation , combinatorial chemistry , organic chemistry , biochemistry , medicine , alternative medicine , pathology

Olefinic CH activation of N ‐allyl sulfonamides in the presence of [{RhCp*Cl 2 } 2 ] (Cp*=Me 5 C 5 ) enabled their oxidative coupling with alkynes to generate 1,2‐dihydropyridines, pyridines, and cyclopentenones (see scheme; Ts= p ‐toluenesulfonyl). The type of highly substituted product formed was controlled by the substitution of the allyl group and the reaction conditions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research