Light‐Induced Modular Ligation of Conventional RAFT Polymers | Zendy

Oehlenschlaeger Kim K. | Zendy; Mueller Jan O. | Zendy; Heine Niklas B. | Zendy; Glassner Mathias | Zendy; Guimard Nathalie K. | Zendy; Delaittre Guillaume | Zendy; Schmidt Friedrich G. | Zendy; BarnerKowollik Christopher | Zendy

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Light‐Induced Modular Ligation of Conventional RAFT Polymers

Author(s) -

Oehlenschlaeger Kim K.,

Mueller Jan O.,

Heine Niklas B.,

Glassner Mathias,

Guimard Nathalie K.,

Delaittre Guillaume,

Schmidt Friedrich G.,

BarnerKowollik Christopher

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206905

Subject(s) - raft , modular design , chain transfer , computer science , reversible addition−fragmentation chain transfer polymerization , polymer , fragmentation (computing) , chemistry , polymerization , organic chemistry , programming language , radical polymerization

Making light work of RAFT conjugation : A non‐activated RAFT agent at the end of RAFT polymers can readily be coupled with ortho ‐quinodimethanes (photoenols) in a photo‐triggered Diels–Alder reaction under mild conditions without catalyst (see scheme). The method is universal and opens the door for the conjugation of a large number of RAFT‐prepared polymers with photoenol‐functionalized (macro)molecules. (RAFT=reversible addition‐fragmentation chain transfer.)

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