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Rational Synthesis for All All ‐Homocalixarenes
Author(s) -
Predeus Alexander V.,
Gopalsamuthiram Vijay,
Staples Richard J.,
Wulff William D.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206785
Subject(s) - generality , annulation , computer science , scheme (mathematics) , content (measure theory) , information retrieval , combinatorial chemistry , world wide web , psychology , chemistry , mathematics , organic chemistry , mathematical analysis , psychotherapist , catalysis
Have it all : The synthesis of homocalixarenes of all sizes has been demonstrated using the triple annulation of bis(carbene) complexes with diynes (see scheme). This strategy in principle should allow access to all homocalixarenes. The generality of the synthetic approach is also demonstrated by the preparation of a pyrrole‐containing calixarene.