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Cover Picture: Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts (Angew. Chem. Int. Ed. 41/2012)
Author(s) -
Feng Dawei,
Gu ZhiYuan,
Li JianRong,
Jiang HaiLong,
Wei Zhangwen,
Zhou HongCai
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206772
Subject(s) - catalysis , porphyrin , isostructural , chemistry , electrospray ionization , zirconium , mesoporous material , mass spectrometry , materials science , combinatorial chemistry , inorganic chemistry , crystallography , organic chemistry , crystal structure , chromatography
Acid‐resistant, water‐stable MOFs with ultra‐large 1D channels exhibiting biomimetic catalytic activity have been developed. In their Communication on page 10307 ff., H.‐C. Zhou and co‐workers report the synthesis, characterization, and catalytic studies of an isostructural series of MOFs designated as PCN‐222. The combination of a zirconium cluster and an iron–porphyrin derivative gave rise to PCN‐222(Fe), which is highly effective in catalyzing the oxidation of a number of peroxidase substrates.