One‐Pot Ring‐Closing Metathesis/1,3‐Dipolar Cycloaddition through Assisted Tandem Ruthenium Catalysis: Synthesis of a Dye with Isoindolo[2,1‐ a ]quinoline Structure | Zendy

Arisawa Mitsuhiro | Zendy; Fujii Yuki | Zendy; Kato Hiroshige | Zendy; Fukuda Hayato | Zendy; Matsumoto Takashi | Zendy; Ito Mika | Zendy; Abe Hiroshi | Zendy; Ito Yoshihiro | Zendy; Shuto Satoshi | Zendy

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One‐Pot Ring‐Closing Metathesis/1,3‐Dipolar Cycloaddition through Assisted Tandem Ruthenium Catalysis: Synthesis of a Dye with Isoindolo[2,1‐ a ]quinoline Structure

Author(s) -

Arisawa Mitsuhiro,

Fujii Yuki,

Kato Hiroshige,

Fukuda Hayato,

Matsumoto Takashi,

Ito Mika,

Abe Hiroshi,

Ito Yoshihiro,

Shuto Satoshi

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206765

Subject(s) - ruthenium , quinoline , substituent , chemistry , aniline , tandem , catalysis , cycloaddition , combinatorial chemistry , ring closing metathesis , conjugated system , metathesis , salt metathesis reaction , ring (chemistry) , molecule , organic chemistry , materials science , polymer , composite material , polymerization

The one‐pot tandem reaction of N ‐alkyl‐ N ‐allyl‐2‐vinylaniline derivatives with benzo‐ or naphthoquinones and a ruthenium–alkylidene catalyst leads to isoindolo[2,1‐ a ]quinolines in a variety of colors, which can be altered by exchanging the substituent on the core heterocycle (see scheme). This reaction offers a new synthetic method for π‐conjugated small molecules from simple aniline derivatives.

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