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Assembly of a Gigantic Polyoxometalate Cluster {W 200 Co 8 O 660 } in a Networked Reactor System
Author(s) -
de la Oliva Andreu Ruiz,
Sans Victor,
Miras Haralampos N.,
Yan Jun,
Zang Hongying,
Richmond Craig J.,
Long DeLiang,
Cronin Leroy
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206572
Subject(s) - polyoxometalate , cluster (spacecraft) , nanotechnology , chemistry , computer science , materials science , chemical engineering , catalysis , operating system , engineering , organic chemistry
A giant leap : A networked reactor system was used for the first time for the discovery and synthesis of new polyoxometalates, including the gigantic title system (see picture; Co red, W blue). The system comprises of three reactors connected in a triangular array with a central triply connected reactor. This system was used to screen multiple one‐pot reactions and reaction variables for the automated syntheses of polyoxometalates.