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Oxidative Geminal Functionalization of Organoboron Compounds
Author(s) -
He Zhi,
Trinchera Piera,
Adachi Shinya,
St. Denis Jeffrey D.,
Yudin Andrei K.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206501
Subject(s) - geminal , organoboron compounds , surface modification , oxidative phosphorylation , chemistry , combinatorial chemistry , organic chemistry , boron , biochemistry
Excellent tolerance : Stable acylboronates equipped with N ‐methyliminodiacetyl (MIDA) boryl groups ( [B] ) were prepared by using a sequence of oxidative manipulations at the boron‐bound carbon center (green in scheme). Chemoselective transformations of these acylated organoboron building blocks yielded a range of multifunctionalized boron derivatives and supplied access to valuable borylated heterocycles (see scheme).