A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes | Zendy

Roşca DragoşAdrian | Zendy; Smith Dan A. | Zendy; Hughes David L. | Zendy; Bochmann Manfred | Zendy

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A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes

Author(s) -

Roşca DragoşAdrian,

Smith Dan A.,

Hughes David L.,

Bochmann Manfred

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206468

Subject(s) - hydride , condensation , regioselectivity , chemistry , reductive elimination , reactivity (psychology) , polymer chemistry , condensation reaction , medicinal chemistry , organic chemistry , metal , catalysis , physics , medicine , alternative medicine , pathology , thermodynamics

Going for gold : The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air‐stable Au II product, [(C N C)* 2 Au 2 ], with a short nonbridged gold–gold bond.

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