The Thiolate‐Catalyzed Intermolecular Crossed Tishchenko Reaction: Highly Chemoselective Coupling of Two Different Aromatic Aldehydes | Zendy

Curran Simon P. | Zendy; Con Stephen J. | Zendy

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The Thiolate‐Catalyzed Intermolecular Crossed Tishchenko Reaction: Highly Chemoselective Coupling of Two Different Aromatic Aldehydes

Author(s) -

Curran Simon P.,

Con Stephen J.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206343

Subject(s) - disproportionation , catalysis , intermolecular force , chemistry , scope (computer science) , functional group , combinatorial chemistry , organic chemistry , molecule , computer science , polymer , programming language

Crossed products : Ortho ‐substituted benzaldehydes react with other aromatic aldehydes in a highly selective, atom‐economical Tishchenko disproportionation (see scheme) in the presence of a readily prepared, inexpensive thiolate‐based catalyst. The methodology is of exceptionally wide scope and exhibits a high functional‐group tolerance.

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