Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes | Zendy

Segarra Candela | Zendy; MasMarzá Elena | Zendy; Benítez Míriam | Zendy; Mata José A. | Zendy; Peris Eduardo | Zendy

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Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes

Author(s) -

Segarra Candela,

MasMarzá Elena,

Benítez Míriam,

Mata José A.,

Peris Eduardo

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206175

Subject(s) - iridium , reactivity (psychology) , rhodium , pyridinium , series (stratigraphy) , chemistry , combinatorial chemistry , medicinal chemistry , information retrieval , computer science , organic chemistry , biology , catalysis , medicine , paleontology , alternative medicine , pathology

Expect the unexpected : The reactions of a series of imidazolium pyridinium salts with [{IrCp*Cl 2 } 2 ] and [{RhCp*Cl 2 } 2 ] afford a series of complexes. Together with the expected bis(NHC) complexes, some species resulting from CC coupling between the pyridylidene and Cp* ligands were observed (see figure; Cp*=pentamethylcyclopentadienyl).

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