Pseudo‐Encapsulation—Nanodomains for Enhanced Reactivity in Ionic Liquids | Zendy

Weber Cameron C. | Zendy; Masters Anthony F. | Zendy; Maschmeyer Thomas | Zendy

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Pseudo‐Encapsulation—Nanodomains for Enhanced Reactivity in Ionic Liquids

Author(s) -

Weber Cameron C.,

Masters Anthony F.,

Maschmeyer Thomas

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201206113

Subject(s) - ionic liquid , cationic polymerization , polar , alkyl , chemistry , nucleophile , encapsulation (networking) , nucleophilic substitution , ionic bonding , ion , combinatorial chemistry , organic chemistry , computer science , catalysis , physics , astronomy , computer network

Domain constrained : Polar and nonpolar domains within 1‐alkyl‐3‐methylimidazolium ionic liquids can affect reaction outcomes by pseudo‐encapsulation of reactants and this has been explored for a nucleophilic substitution reaction using a cationic substrate and a range of nucleophiles. The significant rate enhancements observed correlate with the concentration of the polar reactants within the ionic liquid's polar domain. ([C n MIM]=1‐alkyl‐3‐methylimidazolium).

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