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Lewis Base Stabilized Oxophosphonium Ions
Author(s) -
Hendsbee Arthur D.,
Giffin Nick A.,
Zhang Yaoting,
Pye Cory C.,
Masuda Jason D.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206112
Subject(s) - triethylamine , ion , pyridine , chemistry , monomer , base (topology) , lewis acids and bases , crystal structure , crystallography , medicinal chemistry , organic chemistry , polymer , catalysis , mathematical analysis , mathematics
Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N ‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography.