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Self‐Enhanced Electrochemiluminescence of an Iridium(III) Complex: Mechanistic Insight
Author(s) -
Swanick Kalen N.,
Ladouceur Sébastien,
ZysmanColman Eli,
Ding Zhifeng
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206074
Subject(s) - electrochemiluminescence , iridium , luminophore , excited state , chemistry , photochemistry , materials science , optoelectronics , luminescence , physics , catalysis , atomic physics , biochemistry , electrode
Improved luminophore : The electrochemiluminescence (ECL) of an iridium complex self‐enhanced up to 16 times is reported. Three excited states were observed in the emission spectra (see picture). The ECL efficiency of this complex is the highest reported for an iridium complex.