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A Comparison of the Solid‐State Structures of Halogen Azides XN 3 (X=Cl, Br, I)
Author(s) -
Lyhs Benjamin,
Bläser Dieter,
Wölper Christoph,
Schulz Stephan,
Jansen Georg
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206028
Subject(s) - halogen , solid state , intermolecular force , crystallography , crystal structure , chemistry , materials science , molecule , organic chemistry , alkyl
Delicate crystals : ClN 3 adopts a polymeric structure in the solid state (see picture; N blue, Cl green) with short intermolecular Cl⋅⋅⋅Cl distances, as was observed for the elemental halogen.