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Inside Cover: A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks (Angew. Chem. Int. Ed. 37/2012)
Author(s) -
Guillerm V.,
Ragon F.,
DanHardi M.,
Devic T.,
Vishnuvarthan M.,
Campo B.,
Vimont A.,
Clet G.,
Yang Q.,
Maurin G.,
Férey G.,
Vittadini A.,
Gross S.,
Serre Christian
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201206021
Subject(s) - cover (algebra) , zirconium , int , zirconium oxide , metal organic framework , porosity , oxide , materials science , series (stratigraphy) , metal , chemical engineering , chemistry , inorganic chemistry , computer science , adsorption , metallurgy , engineering , composite material , geology , mechanical engineering , paleontology , operating system
Waterproof MOFs are prepared from the reaction of ZrCl 4 with the corresponding dicarboxylic acid. In their Communication on page 9267 ff., C. Serre and co‐workers show that the members of this new series of isoreticular metal–organic frameworks (MOFs) are hydrophobic, and have a one‐dimensional pore system and Lewis acidity. They also have a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.