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Domino Reactions of Donor–Acceptor‐Substituted Cyclopropanes for the Synthesis of 3,3′‐Linked Oligopyrroles and Pyrrolo[3,2‐ e ]indoles
Author(s) -
Kaschel Johannes,
Schneider Tobias F.,
Kratzert Daniel,
Stalke Dietmar,
Werz Daniel B.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201205880
Subject(s) - domino , acceptor , molecule , chemistry , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , physics , condensed matter physics
Multiple displacement of oxygen : Electron‐rich oligopyrroles and pyrrolo[3,2‐ e ]indoles are generated by a domino process induced by donor–acceptor‐substituted cyclopropanes. Up to seven molecules of water are eliminated, thus allowing the introduction of nitrogen and aromaticity.