Metal‐Mediated Synthesis of 1,4‐Di‐ tert ‐butyl‐1,4‐azaborine | Zendy

Braunschweig Holger | Zendy; Damme Alexander | Zendy; JimenezHalla J. Oscar C. | Zendy; Pfaffinger Bernd | Zendy; Radacki Krzysztof | Zendy; Wolf Justin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Metal‐Mediated Synthesis of 1,4‐Di‐ tert ‐butyl‐1,4‐azaborine

Author(s) -

Braunschweig Holger,

Damme Alexander,

JimenezHalla J. Oscar C.,

Pfaffinger Bernd,

Radacki Krzysztof,

Wolf Justin

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205795

Subject(s) - acetylene , simple (philosophy) , set (abstract data type) , cycloaddition , metal , combinatorial chemistry , chemistry , computer science , information retrieval , stereochemistry , organic chemistry , philosophy , programming language , catalysis , epistemology

Completing the set : Although 1,2‐azaborine is known, little is known about the 1,3‐ and 1,4‐analogues. Now a simple, controlled synthesis of 1,2‐di‐ tert ‐butyl‐1,2‐azaborine from acetylene and di‐ tert ‐butyliminoborane has been achieved by a metal‐mediated formal [2+2+2] cycloaddition reaction. A 1,2‐azaborete pianostool complex was identified as an reaction intermediate.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research