Rhodium‐Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines | Zendy

Ryu Jaeyune | Zendy; Shin Kwangmin | Zendy; Park Sae Hume | Zendy; Kim Ji Young | Zendy; Chang Sukbok | Zendy

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Rhodium‐Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

Author(s) -

Ryu Jaeyune,

Shin Kwangmin,

Park Sae Hume,

Kim Ji Young,

Chang Sukbok

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205723

Subject(s) - amination , rhodium , chemistry , aryl , catalysis , amine gas treating , combinatorial chemistry , functional group , reagent , intermolecular force , substrate (aquarium) , organic chemistry , medicinal chemistry , molecule , alkyl , oceanography , geology , polymer

No muss, no fuss : A rhodium‐catalyzed direct intermolecular CH amination of benzamides and ketoximes using aryl azides as the amine source has been developed. The reaction exhibits a broad substrate scope with excellent functional‐group tolerance, requires no external oxidants, releases N 2 as the only by‐product, and produces diarylamines in high yields.

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