Characterization of a Macrocyclic end‐on Peroxido Copper Complex | Zendy

Hoppe Tobias | Zendy; Schaub Stefan | Zendy; Becker Jonathan | Zendy; Würtele Christian | Zendy; Schindler Siegfried | Zendy

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Characterization of a Macrocyclic end‐on Peroxido Copper Complex

Author(s) -

Hoppe Tobias,

Schaub Stefan,

Becker Jonathan,

Würtele Christian,

Schindler Siegfried

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205663

Subject(s) - copper , adduct , characterization (materials science) , ligand (biochemistry) , chemistry , stereochemistry , crystallography , materials science , nanotechnology , organic chemistry , biochemistry , receptor

Thirty years on : The dinuclear copper peroxido complex [(tet b)CuO 2 Cu(tet b)] 2+ has been structurally characterized (see picture: Cu yellow, O red, N pink; tet b= rac ‐5,5,7,12,12,14‐hexamethyl‐1,4,8,11‐tetraazacyclotetradecane). This complex is quite persistent in solution at room temperature and is the first example of a structurally characterized copper dioxygen adduct complex with a macrocyclic ligand based on earlier studies by Valentine et al.

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