Activation Energy for the Self‐Metalation Reaction of 2H‐Tetraphenylporphyrin on Cu(111) | Zendy

Ditze Stefanie | Zendy; Stark Michael | Zendy; Drost Martin | Zendy; Buchner Florian | Zendy; Steinrück HansPeter | Zendy; Marbach Hubertus | Zendy

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Activation Energy for the Self‐Metalation Reaction of 2H‐Tetraphenylporphyrin on Cu(111)

Author(s) -

Ditze Stefanie,

Stark Michael,

Drost Martin,

Buchner Florian,

Steinrück HansPeter,

Marbach Hubertus

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205464

Subject(s) - tetraphenylporphyrin , metalation , substrate (aquarium) , activation energy , chemistry , kinetic energy , content (measure theory) , energy (signal processing) , molecule , photochemistry , computer science , combinatorial chemistry , stereochemistry , porphyrin , physics , organic chemistry , mathematics , quantum mechanics , oceanography , geology , mathematical analysis

By simply counting individual molecules in STM images after defined heating steps, the kinetic parameters and the activation energy of a complex surface reaction can be determined quantitatively. This procedure was demonstrated for the metalation of 2H‐tetraphenylporphyrin (2HTPP) with substrate atoms on a Cu(111) surface.

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