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Reversible Insertion of Platinum into Coinage Group Metal–Halogen Bonds
Author(s) -
Bauer Jürgen,
Braunschweig Holger,
Damme Alexander,
Radacki Krzysztof
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201205438
Subject(s) - halogen , platinum group , platinum , group (periodic table) , metal , chemistry , organic chemistry , catalysis , alkyl
M&Ms : The reversible insertion of a platinum complex into coinage group metal–halogen bonds results in a series of unsupported metal‐only Lewis pairs with a Lewis basic platinum(0) fragment and cationic copper, silver, and gold Lewis acids (see scheme; M=Cu, Ag, Au; Cy=cyclohexyl). This is a convenient route to mixed d 10 –d 10 complexes.
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