Enforced Planarity: A Strategy for Stable Boron‐Containing π‐Conjugated Materials | Zendy

Araneda Juan F. | Zendy; Neue Benedikt | Zendy; Piers Warren E. | Zendy

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Enforced Planarity: A Strategy for Stable Boron‐Containing π‐Conjugated Materials

Author(s) -

Araneda Juan F.,

Neue Benedikt,

Piers Warren E.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205265

Subject(s) - planarity testing , conjugated system , boron , materials science , polymer chemistry , nanotechnology , photochemistry , chemistry , polymer , organic chemistry , crystallography , composite material

Catching a plane : A new strategy for stabilizing the BC bonds in boron‐containing π‐conjugated materials has been demonstrated. Encasing the boron in a rigid, planarized environment (see scheme) has been shown by Yamaguchi and co‐workers to give air‐ and moisture‐stable organoboranes that bring the boron's p orbital into full conjugation with the organic π framework.

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