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Open‐Shell First‐Row Transition‐Metal Polyhydride Complexes Based on the fac ‐[RuH 3 (PR 3 ) 3 ] − Building Block
Author(s) -
Plois Markus,
Hujo Waldemar,
Grimme Stefan,
Schwickert Christian,
Bill Eckhard,
de Bruin Bas,
Pöttgen Rainer,
Wolf Robert
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201205209
Subject(s) - block (permutation group theory) , hydride , octahedron , crystallography , spin (aerodynamics) , shell (structure) , chemistry , metal , physics , combinatorics , materials science , crystal structure , mathematics , organic chemistry , composite material , thermodynamics
High‐spin hydrides : A new class of stable paramagnetic polyhydride complexes [M{Ru(μ‐H) 3 (PTol 3 ) 3 } 2 ] (M=Cr–Ni) with an unprecedented trinuclear arrangement has been synthesized. The high‐spin central 3d metal ion is sandwiched between six hydride ligands in a distorted octahedral fashion.