Open‐Shell First‐Row Transition‐Metal Polyhydride Complexes Based on the  fac ‐[RuH 3 (PR 3 ) 3 ] −  Building Block | Zendy

Plois Markus | Zendy; Hujo Waldemar | Zendy; Grimme Stefan | Zendy; Schwickert Christian | Zendy; Bill Eckhard | Zendy; de Bruin Bas | Zendy; Pöttgen Rainer | Zendy; Wolf Robert | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Open‐Shell First‐Row Transition‐Metal Polyhydride Complexes Based on the fac ‐[RuH 3 (PR 3 ) 3 ] − Building Block

Author(s) -

Plois Markus,

Hujo Waldemar,

Grimme Stefan,

Schwickert Christian,

Bill Eckhard,

de Bruin Bas,

Pöttgen Rainer,

Wolf Robert

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205209

Subject(s) - block (permutation group theory) , hydride , octahedron , crystallography , spin (aerodynamics) , shell (structure) , chemistry , metal , physics , combinatorics , materials science , crystal structure , mathematics , organic chemistry , composite material , thermodynamics

High‐spin hydrides : A new class of stable paramagnetic polyhydride complexes [M{Ru(μ‐H) 3 (PTol 3 ) 3 } 2 ] (M=Cr–Ni) with an unprecedented trinuclear arrangement has been synthesized. The high‐spin central 3d metal ion is sandwiched between six hydride ligands in a distorted octahedral fashion.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research