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Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides
Author(s) -
Baert François,
Colomb Julie,
Billard Thierry
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201205156
Subject(s) - reagent , electrophile , combinatorial chemistry , fluorine , chemistry , group 2 organometallic chemistry , organic chemistry , organometallic chemistry , computer science , catalysis , molecule
It's so easy! Direct trifluoromethanesulfanylation reactions remain difficult to perform because of the lack of reagents that are stable and easy to handle. Trifluoromethanesulfanamides are reagents which, in combination with readily available Grignard reagents, can be used by those without experience in fluorine chemistry to easily synthesize trifluoromethylthioethers.