Perfluorinated Aromatic Spacers for Sensitizing Europium(III) Centers in Dinuclear Oligomers: Better than the Best by Chemical Design? | Zendy

Lemonnier JeanFrançois | Zendy; Babel Lucille | Zendy; Guénée Laure | Zendy; Mukherjee Prasun | Zendy; Waldeck David H. | Zendy; Eliseeva Svetlana V. | Zendy; Petoud Stéphane | Zendy; Piguet Claude | Zendy

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Perfluorinated Aromatic Spacers for Sensitizing Europium(III) Centers in Dinuclear Oligomers: Better than the Best by Chemical Design?

Author(s) -

Lemonnier JeanFrançois,

Babel Lucille,

Guénée Laure,

Mukherjee Prasun,

Waldeck David H.,

Eliseeva Svetlana V.,

Petoud Stéphane,

Piguet Claude

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205082

Subject(s) - intersystem crossing , europium , quantum yield , chemistry , rational design , yield (engineering) , energy transfer , photochemistry , quantum chemical , fluorine , electron transfer , combinatorial chemistry , computational chemistry , fluorescence , materials science , nanotechnology , molecule , ion , organic chemistry , chemical physics , excited state , atomic physics , physics , quantum mechanics , singlet state , metallurgy

Transfer news : The use of a simple method allows the various sensitization steps in Eu III ‐containing complexes to be deciphered. Incorporation of an increasing number of electron‐withdrawing fluorine atoms on the rigid and electronically tunable phenyl spacer between two tridentate binding units (see picture, red O, dark blue N) affects the quantum yield, intersystem crossing, and energy‐transfer processes in a rational way.

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