Ni/Pd@MIL‐101: Synergistic Catalysis with Cavity‐Conform Ni/Pd Nanoparticles | Zendy

Hermannsdörfer Justus | Zendy; Friedrich Martin | Zendy; Miyajima Nobuyoshi | Zendy; Albuquerque Rodrigo Q. | Zendy; Kümmel Stephan | Zendy; Kempe Rhett | Zendy

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Ni/Pd@MIL‐101: Synergistic Catalysis with Cavity‐Conform Ni/Pd Nanoparticles

Author(s) -

Hermannsdörfer Justus,

Friedrich Martin,

Miyajima Nobuyoshi,

Albuquerque Rodrigo Q.,

Kümmel Stephan,

Kempe Rhett

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205078

Subject(s) - bimetallic strip , nanoparticle , catalysis , composition (language) , metal , metal organic framework , chemistry , computer science , materials science , nanotechnology , chemical engineering , organic chemistry , engineering , philosophy , linguistics , adsorption

A perfect fit : Cavity‐conform bimetallic Ni/Pd nanoparticles of different composition were generated in the metal–organic framework MIL‐101. Experimental evidence and molecular dynamic simulations indicate the existence of mixed bimetallic particles. Pronounced synergistic effects have been observed in liquid‐phase catalysis.

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