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Synthesis, Structure, Tautomerism, and Reactivity of Methanetrisamidines
Author(s) -
Gutschank Benjamin,
Schulz Stephan,
Marcinkowski Michael,
Jansen Georg,
Bandmann Heinz,
Bläser Dieter,
Wölper Christoph
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201205030
Subject(s) - tautomer , reactivity (psychology) , ab initio , computer science , chemistry , computational chemistry , stereochemistry , organic chemistry , medicine , alternative medicine , pathology
Tout au contraire : Both tautomeric forms of a methanetrisamidine were structurally characterized for the first time by X‐ray diffraction and by ab initio calculations (see structures; gray C, red H, blue N). Their reactivity as proton acceptors and multianionic ligands was demonstrated.