Water Oxidation by Single‐Site Ruthenium Complexes: Using Ligands as Redox and Proton Transfer Mediators | Zendy

Kärkäs Markus D. | Zendy; Åkermark Torbjörn | Zendy; Johnston Eric V. | Zendy; Karim Shams R. | Zendy; Laine Tanja M. | Zendy; Lee BaoLin | Zendy; Åkermark Tobias | Zendy; Privalov Timofei | Zendy; Åkermark Björn | Zendy

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Water Oxidation by Single‐Site Ruthenium Complexes: Using Ligands as Redox and Proton Transfer Mediators

Author(s) -

Kärkäs Markus D.,

Åkermark Torbjörn,

Johnston Eric V.,

Karim Shams R.,

Laine Tanja M.,

Lee BaoLin,

Åkermark Tobias,

Privalov Timofei,

Åkermark Björn

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201205018

Subject(s) - ruthenium , redox , chemistry , imidazole , photochemistry , catalysis , proton , bipyridine , combinatorial chemistry , inorganic chemistry , stereochemistry , crystallography , organic chemistry , crystal structure , physics , quantum mechanics

Light me up : Through the use of an imidazole motif it is possible to introduce a combined redox and proton‐transfer mediator into single‐site ruthenium water‐oxidation catalysts. With the complex (see picture), high turnover numbers and high initial turnover frequencies were attained with the mild oxidant [Ru(bpy) 3 ] 3+ (bpy=2,2′‐bipyridine).

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