Differentiation of Highly Anisotropic Tb III  and Dy III  with  57 Fe Mössbauer Spectroscopy | Zendy

Mereacre Valeriu | Zendy

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Differentiation of Highly Anisotropic Tb III and Dy III with 57 Fe Mössbauer Spectroscopy

Author(s) -

Mereacre Valeriu

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204838

Subject(s) - mössbauer spectroscopy , anisotropy , ion , spectroscopy , crystal (programming language) , mössbauer effect , crystallography , materials science , x ray spectroscopy , field (mathematics) , analytical chemistry (journal) , atomic physics , chemistry , physics , optics , programming language , organic chemistry , chromatography , quantum mechanics , computer science , mathematics , pure mathematics

Using 57 Fe Mössbauer spectroscopy, three examples of coordination compounds with different topologies containing Fe III and Ln III ions (Dy III and Tb III ; see diagram; insets: clusters cores) were analyzed. In the same crystal field environment, Dy and Tb ions show different degrees of anisotropy, which can be qualitatively detected using an indirect method.

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