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A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks
Author(s) -
Guillerm V.,
Ragon F.,
DanHardi M.,
Devic T.,
Vishnuvarthan M.,
Campo B.,
Vimont A.,
Clet G.,
Yang Q.,
Maurin G.,
Férey G.,
Vittadini A.,
Gross S.,
Serre Christian
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204806
Subject(s) - zirconium , porosity , metal organic framework , hydrothermal circulation , oxide , chemical engineering , chemistry , materials science , inorganic chemistry , polymer chemistry , organic chemistry , adsorption , engineering
Brolly good MOFs : A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one‐dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.