A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks | Zendy

Guillerm V. | Zendy; Ragon F. | Zendy; DanHardi M. | Zendy; Devic T. | Zendy; Vishnuvarthan M. | Zendy; Campo B. | Zendy; Vimont A. | Zendy; Clet G. | Zendy; Yang Q. | Zendy; Maurin G. | Zendy; Férey G. | Zendy; Vittadini A. | Zendy; Gross S. | Zendy; Serre Christian | Zendy

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A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks

Author(s) -

Guillerm V.,

Ragon F.,

DanHardi M.,

Devic T.,

Vishnuvarthan M.,

Campo B.,

Vimont A.,

Clet G.,

Yang Q.,

Maurin G.,

Férey G.,

Vittadini A.,

Gross S.,

Serre Christian

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204806

Subject(s) - zirconium , porosity , metal organic framework , hydrothermal circulation , oxide , chemical engineering , chemistry , materials science , inorganic chemistry , polymer chemistry , organic chemistry , adsorption , engineering

Brolly good MOFs : A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one‐dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.

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