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Solution‐Phase and Magnetic Approach towards Understanding Iron Gall Ink‐like Nanoassemblies
Author(s) -
Kumari Harshita,
Kline Steven R.,
Dennis Cindi L.,
Mossine Andrew V.,
Paul Rick L.,
Deakyne Carol A.,
Atwood Jerry L.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204776
Subject(s) - materials science , nanotechnology , metal , phase (matter) , chemical engineering , chemistry , metallurgy , engineering , organic chemistry
Metal‐containing tubes : The structures of several iron‐containing C ‐methylpyrogallol[4]arene (PgC 1 ) nanoassemblies were studied in both the solid and solution phases. The nanoassemblies have a tubular architecture with the iron as part of the framework (see picture; gray C, red O, turquoise/blue Fe), and magnetic analysis suggests a canted or spiral arrangement of the iron centers.