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A Conjunctive Carboiodination: Indenes by a Double Carbopalladation–Reductive Elimination Domino Process
Author(s) -
Jia Xiaodong,
Petrone David A.,
Lautens Mark
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204716
Subject(s) - domino , intramolecular force , nothing , ring (chemistry) , computer science , intermolecular force , chemistry , philosophy , stereochemistry , catalysis , organic chemistry , molecule , epistemology
Something gained, nothing lost : A Pd 0 ‐catalyzed domino intermolecular/intramolecular process terminated by carbohalogenation is reported. In this reaction, two new CC bonds, one new CI bond and one five‐membered ring are formed in a single step, and all of the atoms in the starting materials are incorporated into the product (see scheme).