NHC‐Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene–Zinc Complexes | Zendy

Wang Yuzhong | Zendy; Xie Yaoming | Zendy; Abraham Mariham Y. | Zendy; Gilliard Robert J. | Zendy; Wei Pingrong | Zendy; Campana Charles F. | Zendy; Schaefer Henry F. | Zendy; Schleyer Paul von R. | Zendy; Robinson Gregory H. | Zendy

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NHC‐Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene–Zinc Complexes

Author(s) -

Wang Yuzhong,

Xie Yaoming,

Abraham Mariham Y.,

Gilliard Robert J.,

Wei Pingrong,

Campana Charles F.,

Schaefer Henry F.,

Schleyer Paul von R.,

Robinson Gregory H.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204712

Subject(s) - carbene , zinc , chemistry , ring (chemistry) , transformation (genetics) , stereochemistry , polymer chemistry , organic chemistry , catalysis , biochemistry , gene

Anion is superior : NHC‐based triorganozincates, from mononuclear to trinuclear, have been synthesized. The NHC‐based triorganozincate chain (see scheme; left) was transformed into an abnormal carbene ( a NHC)‐complexed zinc ring (right) by reaction with MeOTf, closing the a NHC‐Group 12 complexes gap.

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