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Inside Back Cover: Electrochemical Mapping Reveals Direct Correlation between Heterogeneous Electron‐Transfer Kinetics and Local Density of States in Diamond Electrodes (Angew. Chem. Int. Ed. 28/2012)
Author(s) -
Patten Hollie V.,
Meadows Katherine E.,
Hutton Laura A.,
Iacobini James G.,
Battistel Dario,
McKelvey Kim,
Colburn Alexander W.,
Newton Mark E.,
Macpherson Julie V.,
Unwin Patrick R.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204563
Subject(s) - diamond , electrode , electron transfer , raman spectroscopy , electrochemistry , kinetics , cover (algebra) , materials science , dopant , doping , microscopy , electron , analytical chemistry (journal) , chemistry , optoelectronics , optics , physics , mechanical engineering , quantum mechanics , chromatography , composite material , engineering
A Multi‐Microscopy Approach has allowed electrochemical reaction rates to be linked to the corresponding dopant levels in polycrystalline boron‐doped diamond electrodes. In their Communication on page 7002 ff., P. R. Unwin, J. V. Macpherson, et al. combine high‐resolution electrochemical imaging, micro‐Raman, and electron‐microscopy data to demonstrate that spatially heterogeneous electron‐transfer kinetics correlate directly with the local density of electronic states.