Inside Cover: Watching Water Migration around a Peptide Bond (Angew. Chem. Int. Ed. 27/2012) | Zendy

Tanabe Kohei | Zendy; Miyazaki Mitsuhiko | Zendy; Schmies Matthias | Zendy; Patzer Alexander | Zendy; Schütz Markus | Zendy; Sekiya Hiroshi | Zendy; Sakai Makoto | Zendy; Dopfer Otto | Zendy; Fujii Masaaki | Zendy

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Inside Cover: Watching Water Migration around a Peptide Bond (Angew. Chem. Int. Ed. 27/2012)

Author(s) -

Tanabe Kohei,

Miyazaki Mitsuhiko,

Schmies Matthias,

Patzer Alexander,

Schütz Markus,

Sekiya Hiroshi,

Sakai Makoto,

Dopfer Otto,

Fujii Masaaki

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204562

Subject(s) - ligand (biochemistry) , peptide , acetanilide , chemistry , molecule , hydrogen bond , peptide bond , stereochemistry , receptor , organic chemistry , biochemistry

The motion of a single water ligand around a peptide bond in acetanilide was probed in real time by time‐resolved IR spectroscopy. In their Communication on page 6604 ff. , O. Dopfer, M. Fujii et al. observe that triggered by photo‐ionization, the H 2 O ligand is released from the CO site of the peptide linkage and trapped after a migration time of 5 ps at the NH site of the same peptide bond. The migration occurs via an intermediate in which the H 2 O molecule binds neither to the CO nor the NH site.

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