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Hexaphyrin Fused to Two Anthracenes
Author(s) -
Naoda Koji,
Mori Hirotaka,
Aratani Naoki,
Lee Byung Sun,
Kim Dongho,
Osuka Atsuhiro
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204446
Subject(s) - redox , chemistry , frame (networking) , benzoquinone , photochemistry , crystallography , stereochemistry , inorganic chemistry , organic chemistry , computer science , telecommunications
Gold standard : A bis(Au III ) complex containing the title compound was prepared and characterized (see scheme; DDQ=2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone, Tf=trifluoromethanesulfonyl). Owing to the effective conjugative network over the flat and elongated rectangular molecular frame, this complex displays a remarkably red‐shifted and sharp Q‐band‐like band at 1467 nm, multiple reversible redox potentials, and a large TPA cross‐section value.