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Highly Enantioselective Catalytic [6+3] Cycloadditions of Azomethine Ylides
Author(s) -
Potowski Marco,
Bauer Jonathan O.,
Strohmann Carsten,
Antonchick Andrey P.,
Waldmann Herbert
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204394
Subject(s) - enantioselective synthesis , stereocenter , cycloaddition , sequence (biology) , catalysis , computer science , chemistry , combinatorial chemistry , stereochemistry , organic chemistry , biochemistry
Under control : Highly functionalized chiral annulated piperidines with eight stereocenters are efficiently obtained by means of a highly enantioselective one‐pot [6+3]/[4+2] sequence. This sequence included the first enantioselective [6+3] cycloaddition of azomethine ylides with fulvenes.