Expeditious Synthesis of Tetrasubstituted Helical Alkenes by a Cascade of Palladium‐Catalyzed CH Activations | Zendy

Liu Hongqiang | Zendy; ElSalfiti Mohamed | Zendy; Lautens Mark | Zendy

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Expeditious Synthesis of Tetrasubstituted Helical Alkenes by a Cascade of Palladium‐Catalyzed CH Activations

Author(s) -

Liu Hongqiang,

ElSalfiti Mohamed,

Lautens Mark

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204226

Subject(s) - palladium , domino , norbornene , cascade reaction , catalysis , intermolecular force , chemistry , cascade , molecule , combinatorial chemistry , stereochemistry , sequence (biology) , organic chemistry , biochemistry , monomer , chromatography , polymer

Twisted molecules : A modular approach for the synthesis of tetrasubstituted helical alkenes by a palladium‐catalyzed norbornene‐mediated domino reaction is presented. This intermolecular domino process allows the formation of three CC bonds in one operation through a CH activation/carbopalladation/CH activation sequence.

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