Selective Reduction of Aqueous Protons to Hydrogen with a Synthetic Cobaloxime Catalyst in the Presence of Atmospheric Oxygen | Zendy

Lakadamyali Fezile | Zendy; Kato Masaru | Zendy; Muresan Nicoleta M. | Zendy; Reisner Erwin | Zendy

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Selective Reduction of Aqueous Protons to Hydrogen with a Synthetic Cobaloxime Catalyst in the Presence of Atmospheric Oxygen

Author(s) -

Lakadamyali Fezile,

Kato Masaru,

Muresan Nicoleta M.,

Reisner Erwin

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204180

Subject(s) - catalysis , hydrogen , aqueous solution , cobalt , homogeneous , oxygen , inorganic chemistry , chemistry , atmospheric pressure , faraday efficiency , photochemistry , materials science , electrochemistry , organic chemistry , thermodynamics , electrode , meteorology , physics

Protons preferred : A cobalt catalyst is reported that evolves H 2 electro‐ and photocatalytically at room temperature, in pH‐neutral water, and in the presence of atmospheric O 2 (see scheme). The catalyst shows respectable Faradaic efficiencies under N 2 and 21 % O 2 in N 2 , and can be used under both homogeneous and heterogeneous conditions.

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