Ligand‐Accelerated Activation of Strong CH Bonds of Alkanes by a (Salen)ruthenium(VI)–Nitrido Complex | Zendy

Man WaiLun | Zendy; Lam William W. Y. | Zendy; Kwong HoiKi | Zendy; Yiu ShekMan | Zendy; Lau TaiChu | Zendy

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Ligand‐Accelerated Activation of Strong CH Bonds of Alkanes by a (Salen)ruthenium(VI)–Nitrido Complex

Author(s) -

Man WaiLun,

Lam William W. Y.,

Kwong HoiKi,

Yiu ShekMan,

Lau TaiChu

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204136

Subject(s) - ruthenium , chemistry , ligand (biochemistry) , limiting , alkane , intermolecular force , combinatorial chemistry , catalysis , photochemistry , stereochemistry , polymer chemistry , organic chemistry , molecule , mechanical engineering , biochemistry , receptor , engineering

Kinetic and mechanistic studies on the intermolecular activation of strong CH bonds of alkanes by a (salen)ruthenium(VI) nitride were performed. The initial, rate‐limiting step, the hydrogen atom transfer (HAT) from the alkane to Ru VI N, generates Ru V NH and RC . HCH 2 R. The following steps involve N‐rebound and desaturation.

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