Picking up 30 CO 2  Molecules by a Porous Metal Oxide Capsule Based on the Same Number of Receptors | Zendy

Garai Somenath | Zendy; Haupt Erhard T. K. | Zendy; Bögge Hartmut | Zendy; Merca Alice | Zendy; Müller Achim | Zendy

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Picking up 30 CO 2 Molecules by a Porous Metal Oxide Capsule Based on the Same Number of Receptors

Author(s) -

Garai Somenath,

Haupt Erhard T. K.,

Bögge Hartmut,

Merca Alice,

Müller Achim

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201204089

Subject(s) - capsule , linker , receptor , oxide , chemistry , molecule , porosity , molybdenum oxide , metal , organic chemistry , biochemistry , computer science , biology , botany , operating system

30 receptors in waiting position : In the porous (pentagon) 12 (linker) 30 ‐type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO 3 2− ligands) can act as receptors for neutral and negatively charged ligands. Bubbling CO 2 into the solution containing the acetate‐type capsules leads to the upload of CO 2 based on 30 coordinated CO 3 2− ligands.

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