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Picking up 30 CO 2 Molecules by a Porous Metal Oxide Capsule Based on the Same Number of Receptors
Author(s) -
Garai Somenath,
Haupt Erhard T. K.,
Bögge Hartmut,
Merca Alice,
Müller Achim
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204089
Subject(s) - capsule , linker , receptor , oxide , chemistry , molecule , porosity , molybdenum oxide , metal , organic chemistry , biochemistry , computer science , biology , botany , operating system
30 receptors in waiting position : In the porous (pentagon) 12 (linker) 30 ‐type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO 3 2− ligands) can act as receptors for neutral and negatively charged ligands. Bubbling CO 2 into the solution containing the acetate‐type capsules leads to the upload of CO 2 based on 30 coordinated CO 3 2− ligands.