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Enantioselective Rhodium‐Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents
Author(s) -
Luo Yunfei,
Hepburn Hamish B.,
Chotsaeng Nawasit,
Lam Hon Wai
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201204004
Subject(s) - enantioselective synthesis , nucleophile , electrophile , rhodium , chemistry , reagent , catalysis , combinatorial chemistry , nucleophilic addition , organic chemistry
Chiral allylrhodium nucleophiles : The highly diastereo‐ and enantioselective title reaction of a range of cyclic imines with various potassium allyltrifluoroborates most likely proceeds via allylrhodium(I) intermediates, and represents the first rhodium‐catalyzed enantioselective nucleophilic allylation of π electrophiles with allylboron compounds.
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