[Co(η 5 ‐P 5 ){η 2 ‐P 2 H(mes)}] 2− : A Phospha‐Organometallic Complex Obtained by the Transition‐Metal‐Mediated Activation of the Heptaphosphide Trianion | Zendy

Knapp Caroline M. | Zendy; Westcott Bethan H. | Zendy; Raybould Melissa A. C. | Zendy; McGrady John E. | Zendy; Goicoechea Jose M. | Zendy

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[Co(η 5 ‐P 5 ){η 2 ‐P 2 H(mes)}] 2− : A Phospha‐Organometallic Complex Obtained by the Transition‐Metal‐Mediated Activation of the Heptaphosphide Trianion

Author(s) -

Knapp Caroline M.,

Westcott Bethan H.,

Raybould Melissa A. C.,

McGrady John E.,

Goicoechea Jose M.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203980

Subject(s) - group 2 organometallic chemistry , cobalt , transition metal , chemistry , yield (engineering) , cluster (spacecraft) , metal , crystallography , physics , molecule , inorganic chemistry , organic chemistry , catalysis , computer science , programming language , thermodynamics

A carbon copy : The chemical activation of the heptaphosphide trianion with [Co(PEt 2 Ph) 2 (mes) 2 ] (see picture; 1 ) yields the novel phospha‐organometallic complex [Co(η 5 ‐P 5 ){η 2 ‐P 2 H(mes)}] 2− ( 2 ). The reaction product maintains the nuclearity of the parent cluster, but extensive cage fragmentation takes place to yield a diamagnetic “inorganometallic” cobalt complex.

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