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Room‐Temperature Photoinduced Electron Transfer in a Prussian Blue Analogue under Hydrostatic Pressure
Author(s) -
Cafun JeanDaniel,
Lejeune Julien,
Baudelet François,
Dumas Paul,
Itié JeanPaul,
Bleuzen Anne
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203943
Subject(s) - prussian blue , blueshift , hydrostatic pressure , materials science , spectroscopy , absorption (acoustics) , irradiation , analytical chemistry (journal) , electron , energy transfer , hydrostatic equilibrium , absorption spectroscopy , chemistry , photochemistry , optics , optoelectronics , molecular physics , electrochemistry , physics , photoluminescence , electrode , quantum mechanics , composite material , thermodynamics , chromatography , nuclear physics
In from the cold : The Co III Fe II state of a CoFe Prussian blue analogue undergoes a Co III Fe II →(Co II Fe III )* electron transfer at room temperature when irradiated by visible light (532 nm; see scheme). This property was confirmed using energy‐dispersive X‐ray absorption spectroscopy at the Co and Fe K‐edges of the piezo‐induced Co III Fe II state.