Premium
Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3‐Dihydride‐2‐iodidecyclotetraphosphane
Author(s) -
Barbaro Pierluigi,
Bazzicalupi Carla,
Peruzzini Maurizio,
Seniori Costantini Stefano,
Stoppioni Piero
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203908
Subject(s) - white phosphorus , cyclopentadienyl complex , iodine , ruthenium , phosphorus , chemistry , hydrolysis , inorganic chemistry , catalysis , organic chemistry
Double stabilization : Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P 4 ) coordinated between two CpRu(PPh 3 ) 2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P 4 H 2 I, P 4 H 2 , P 3 H 5 ; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers.