Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3‐Dihydride‐2‐iodidecyclotetraphosphane | Zendy

Barbaro Pierluigi | Zendy; Bazzicalupi Carla | Zendy; Peruzzini Maurizio | Zendy; Seniori Costantini Stefano | Zendy; Stoppioni Piero | Zendy

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Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3‐Dihydride‐2‐iodidecyclotetraphosphane

Author(s) -

Barbaro Pierluigi,

Bazzicalupi Carla,

Peruzzini Maurizio,

Seniori Costantini Stefano,

Stoppioni Piero

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203908

Subject(s) - white phosphorus , cyclopentadienyl complex , iodine , ruthenium , phosphorus , chemistry , hydrolysis , inorganic chemistry , catalysis , organic chemistry

Double stabilization : Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P 4 ) coordinated between two CpRu(PPh 3 ) 2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P 4 H 2 I, P 4 H 2 , P 3 H 5 ; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers.

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