Mechanistic Insights into a Supramolecular Self‐Assembling Catalyst System: Evidence for Hydrogen Bonding during Rhodium‐Catalyzed Hydroformylation | Zendy

Gellrich Urs | Zendy; Seiche Wolfgang | Zendy; Keller Manfred | Zendy; Breit Bernhard | Zendy

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Mechanistic Insights into a Supramolecular Self‐Assembling Catalyst System: Evidence for Hydrogen Bonding during Rhodium‐Catalyzed Hydroformylation

Author(s) -

Gellrich Urs,

Seiche Wolfgang,

Keller Manfred,

Breit Bernhard

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203768

Subject(s) - hydroformylation , rhodium , catalysis , supramolecular chemistry , intermolecular force , hydrogen bond , chemistry , combinatorial chemistry , ligand (biochemistry) , catalytic cycle , organic chemistry , molecule , biochemistry , receptor

The structural integrity and flexibility provided by intermolecular hydrogen bonds leads to the outstanding properties of the 6‐diphenylphosphinopyridin‐(2 H )‐1‐one ligand (see scheme) in the rhodium‐catalyzed hydroformylation of terminal alkenes, as demonstrated by the combination of spectroscopic methods and DFT computations. Hydrogen bonds were also detected in a competent intermediate of the catalytic cycle.

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