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Post‐Synthetic Modification of Porphyrin‐Encapsulating Metal–Organic Materials by Cooperative Addition of Inorganic Salts to Enhance CO 2 / CH 4 Selectivity
Author(s) -
Zhang Zhenjie,
Gao WenYang,
Wojtas Lukasz,
Ma Shengqian,
Eddaoudi Mohamed,
Zaworotko Michael J.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201203594
Subject(s) - cationic polymerization , microporous material , porphyrin , chemistry , biphenyl , tetra , metal organic framework , solvent , metal , stoichiometry , combinatorial chemistry , polymer chemistry , organic chemistry , medicinal chemistry , adsorption
Keeping MOM : Reaction of biphenyl‐3,4′,5‐tricarboxylate and Cd(NO 3 ) 2 in the presence of meso ‐tetra( N ‐methyl‐4‐pyridyl)porphine tetratosylate afforded porph@MOM‐11, a microporous metal–organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM‐11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M + Cl − ) in a stoichiometric fashion.