Post‐Synthetic Modification of Porphyrin‐Encapsulating Metal–Organic Materials by Cooperative Addition of Inorganic Salts to Enhance CO 2  / CH 4  Selectivity | Zendy

Zhang Zhenjie | Zendy; Gao WenYang | Zendy; Wojtas Lukasz | Zendy; Ma Shengqian | Zendy; Eddaoudi Mohamed | Zendy; Zaworotko Michael J. | Zendy

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Post‐Synthetic Modification of Porphyrin‐Encapsulating Metal–Organic Materials by Cooperative Addition of Inorganic Salts to Enhance CO 2 / CH 4 Selectivity

Author(s) -

Zhang Zhenjie,

Gao WenYang,

Wojtas Lukasz,

Ma Shengqian,

Eddaoudi Mohamed,

Zaworotko Michael J.

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203594

Subject(s) - cationic polymerization , microporous material , porphyrin , chemistry , biphenyl , tetra , metal organic framework , solvent , metal , stoichiometry , combinatorial chemistry , polymer chemistry , organic chemistry , medicinal chemistry , adsorption

Keeping MOM : Reaction of biphenyl‐3,4′,5‐tricarboxylate and Cd(NO 3 ) 2 in the presence of meso ‐tetra( N ‐methyl‐4‐pyridyl)porphine tetratosylate afforded porph@MOM‐11, a microporous metal–organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM‐11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M + Cl − ) in a stoichiometric fashion.

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