Hydrogen Production Using a Molybdenum Sulfide Catalyst on a Titanium‐Protected n + p‐Silicon Photocathode | Zendy

Seger Brian | Zendy; Laursen Anders B. | Zendy; Vesborg Peter C. K. | Zendy; Pedersen Thomas | Zendy; Hansen Ole | Zendy; Dahl Søren | Zendy; Chorkendorff Ib | Zendy

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Hydrogen Production Using a Molybdenum Sulfide Catalyst on a Titanium‐Protected n + p‐Silicon Photocathode

Author(s) -

Seger Brian,

Laursen Anders B.,

Vesborg Peter C. K.,

Pedersen Thomas,

Hansen Ole,

Dahl Søren,

Chorkendorff Ib

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203585

Subject(s) - photocathode , silicon , oxidizing agent , titanium , materials science , molybdenum , catalysis , sulfide , hydrogen production , inorganic chemistry , electrode , metallurgy , chemistry , biochemistry , physics , organic chemistry , quantum mechanics , electron

A low‐cost substitute : A titanium protection layer on silicon made it possible to use silicon under highly oxidizing conditions without oxidation of the silicon. Molybdenum sulfide was electrodeposited on the Ti‐protected n + p‐silicon electrode. This electrode was applied as a photocathode for water splitting and showed a greatly enhanced efficiency.

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