Intermolecular Gold‐Catalyzed Diastereo‐ and Enantioselective [2+2+3] Cycloadditions of 1,6‐Enynes with Nitrones | Zendy

Gawade Sagar Ashok | Zendy; Bhunia Sabyasachi | Zendy; Liu RaiShung | Zendy

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Intermolecular Gold‐Catalyzed Diastereo‐ and Enantioselective [2+2+3] Cycloadditions of 1,6‐Enynes with Nitrones

Author(s) -

Gawade Sagar Ashok,

Bhunia Sabyasachi,

Liu RaiShung

Publication year - 2012

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201203507

Subject(s) - enantioselective synthesis , scope (computer science) , intermolecular force , scheme (mathematics) , substrate (aquarium) , chemistry , catalysis , computer science , combinatorial chemistry , information retrieval , organic chemistry , mathematics , biology , programming language , molecule , ecology , mathematical analysis

Going for gold : The title reaction has been developed and demonstrates a wide substrate scope with respect to the 1,6‐enynes and nitrones (see scheme; DCE=1,2‐dichloroethane, Tf=trifluoromethanesulfonyl). The results for the enantioselective versions are also presented.

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